Title of article
Two trimeric tri-TiIV-substituted Keggin tungstogermanates based on tetrahedral linkers
Author/Authors
Yuanhang Ren، نويسنده , , Shu-Xia Liu، نويسنده , , Rui-Ge Cao، نويسنده , , Xinyu Zhao، نويسنده , , Jian-Fang Cao، نويسنده , , Chao-Ying Gao، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
1320
To page
1322
Abstract
Two trimeric nine-TiIV contained tungstogermanates K14{K ⊂ [(Ge(OH)O3)(GeW9Ti3O38H2)3]} · 42H2O 1 and K10{K ⊂ [(SO4)(GeW9Ti3O38H3)3] · 40H2O 2 have been conventionally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. They were constructed from three tri-substituted A-α-[GeW9Ti3O38] and GeO4/SO4 tetrahedral linker. They display the first example of trimeric titanium-substituted tungstogermanates, which contain both Ti–O–Ti and Ti–O–Ge/Ti–O–S bridges.
Keywords
Titanium , Conventional synthesis , Keggin , Tungstogermanate
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317956
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