Title of article
Synthesis, characterization and catalytic properties of an N-heterocyclic carbene palladium-based complex
Author/Authors
Ismail Ozdemir، نويسنده , , Hakan Arslan، نويسنده , , Serpil Demir، نويسنده , , Don Vanderveer، نويسنده , , Bekir Cetinkaya، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
4
From page
1462
To page
1465
Abstract
A palladium(II) complex, bis[1,3-bis-(2,4,6-trimethylbenzyl)benzimidazol-2-ylidene]palladium(II) chloride, Pd(NHC), bearing N-heterocyclic carbenes has been synthesized and characterized by elemental analysis, IR spectroscopy and 1H and 13C NMR spectroscopy. Crystal structure details of Pd(NHC) are also presented. The palladium centre in the complex lies on a crystallographic inversion centre and occupies a square-planar environment, with both chloride and N-heterocyclic carbene ligands adopting a trans arrangement with Cl–Pd–Cl and C–Pd–C angles are precisely 180°. The palladium–carbene complex was tested as a catalyst in the Suzuki–Miyaura cross-coupling reaction.
Keywords
Suzuki–Miyaura cross-coupling reaction , Palladium catalyst , N-heterocyclic carbenes , Palladium–carbene complexes , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317980
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