Title of article
A lead(II)-orotate coordination polymer with a new coordination mode: Synthesis, structure and luminescent property
Author/Authors
Hua Yin، نويسنده , , Shixiong Liu، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
4
From page
187
To page
190
Abstract
A lead(II) orotate complex [Pb(HOr)(H2O)]n (1), (H3Or = orotic acid) was synthesized under hydrothermal condition and characterized by X-ray diffraction, IR, solid-state photoluminescence and thermogravimetric analysis. Lead atom in 1 is in a holodirected eight-coordinated polyhedron and the orotate ligand exhibits a new and unique hexametallic coordination mode. The lead complex shows a 6,6-connected (48, 66, 8)(413, 62) topology. The complex exhibits photoluminescence at 546 nm (λex = 350 nm).
Keywords
Complex , crystal structure , topology , Luminescent property , Lead(II)
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318038
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