Title of article
A 3D photoluminescent cadmium(II)-organic framework with unusual pentanuclear cluster as secondary building unit
Author/Authors
En-Cui Yang، نويسنده , , Qing-Qing Liang، نويسنده , , Peng Wang، نويسنده , , Xiao-Jun Zhao، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
3
From page
211
To page
213
Abstract
A crystalline 3D MOF with unique pentanuclear Cd(II)-cluster as SBU, [Cd5(H2O)4(ap)3(trz)4]n (1) (H2ap = adipic acid, Htrz = 1,2,4-triazole), was isolated by hydrothermal method, which exhibits strong Htrz-based luminescent emission. More interestingly, ap ligands in 1 were observed to play the important roles for both the aggregate of polynuclear motif and the extension of the infinite 3D framework.
Keywords
1 , Pentanuclear cluster , 4-Triazole , 2 , Secondary building unit , Metal-organic framework
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318045
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