Title of article
Synthesis, structure and stability of fac-[FeII(CO)3X3]1− (X = Br, I)
Author/Authors
Jianfeng Jiang، نويسنده , , Wenfeng Lo، نويسنده , , Peter Müller، نويسنده , , Noam D. Fine، نويسنده , , Myrium Maruani، نويسنده , , Alexander Raytman، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
3
From page
527
To page
529
Abstract
fac-[FeII(CO)3X3]1− (X = Br, I) are synthesized and their structures have been determined. They are the first crystallographically characterized iron tricarbonyl trihalide complexes. fac-[FeII(CO)3X3]1− (X = Br, I) are fairly thermally stable and therefore lead themselves as excellent starting materials for the preparation of various iron carbonyl complexes since both the halide and carbonyl ligands are substitutionally labile.
Keywords
Iron carbonyl halides , X-ray structure , Infrared , Stability
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318130
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