• Title of article

    The first polypseudo-rotaxane structure based on the Wells–Dawson polyoxometalate

  • Author/Authors

    Pengpeng Zhang، نويسنده , , Aixiang Tian، نويسنده , , Jun Peng، نويسنده , , Haijun Pang، نويسنده , , Jingquan Sha، نويسنده , , Yuan Chen، نويسنده , , Min Zhu، نويسنده , , Yonghui Wang، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2009
  • Pages
    3
  • From page
    902
  • To page
    904
  • Abstract
    A polyoxometalate-based compound, (bix)[Cu(bix)][Cu2(bix)2(P2W18O62)]·2H2O (1) (bix = 1,4-bis(imidazol-1-ylmethyl)benzene), was hydrothermally synthesized, and characterized by elemental analyses, IR spectroscopy, thermogravimetric analysis, and single X-ray diffraction. Compound 1 exhibits the 1D + 1D polypseudo-rotaxane structure consists of two parts: the P2W18–Cu2–(bix)2 chain which contains 26-membered Cu2(bix)2 macrocycles and the 1D Cu-bix line. Remarkably, it represents the first polypseudo-rotaxane structure based on the Wells–Dawson polyoxometalate.
  • Keywords
    Wells–Dawson polyoxometalate , Hydrothermal synthesis , Polypseudo-rotaxane
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2009
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1318232