Author/Authors :
Fabio Lorenzini، نويسنده , , Eoghain O’Hara، نويسنده , , Shimeng Qian، نويسنده , , Fabio Marchetti، نويسنده , , James M. Birbeck، نويسنده , , Anthony Haynes، نويسنده , , Alexander J. Blake، نويسنده , , Graham C. Saunders، نويسنده , , Andrew C. Marr، نويسنده ,
Abstract :
Rh2(cod)2(μ2-dppm)(μ2-Cl)]BF4 (1) rearranges under carbon monoxide to give [Rh3(μ2-dppm)2(μ2-CO)3(K1-CO)3]BF4 (2). Complex 2 has been structurally characterized by single crystal X-ray crystallography. The hydroformylation activities of 1 and 2 were compared for substrates styrene and 1-hexene and the activity of 2 found to be unexpectedly high.
Keywords :
Binuclear , Trinuclear , Rhodium , hydroformylation
