Title of article :
A new sandwich-type polyoxometalate constructed from penta-lacunary [HPW7O28]8− units and MnIII ion
Author/Authors :
Qiong Wu، نويسنده , ,
Yangguang Li، نويسنده , , Yonghui Wang، نويسنده , , Zhiming Zhang، نويسنده , , En-Bo Wang، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
A new sandwich-type polyoxometalate (POM) K12Na1[(HPW7O28)2Mn]·17.5H2O (1) has been synthesized and characterized by elemental analysis, IR, TG, UV as well as single-crystal X-ray diffraction analysis. Compound 1 represents the first sandwich-type POM constructed by the penta-lacunary heptatungstophosphate [HPW7O28]8− moieties. Moreover, compound 1 exhibits good electrocatalytic properties to reduce the nitrite.
Keywords :
Polyoxometalate , Heptatungstophosphate , manganese , Sandwich-type , Electrocatalysis
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
