Title of article :
Ru(II)–CO complexes of thioarylazoimidazoles: Syntheses, structures, spectroscopy and DFT calculation
Author/Authors :
T.K. Mondal، نويسنده , , P. Raghavaiah، نويسنده , , A.K. Patra، نويسنده , , C. Sinha، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
The complexes, cis-(CO)-trans-(Cl)-[Ru(SRaaiNR)(CO)2Cl2] (2) and trans-(Cl)-[Ru(SRaaiNR)(CO)Cl2] (3) (SRaaiNR = 1-alkyl-2-{(o-thioalkyl)phenylazo}imidazoles; R = Me (1a) and Et (1b)) have been synthesized and characterized. The structural confirmation is achieved by single crystal X-ray structure determinations. The complexes show Ru(III)/Ru(II) couple and ligand reductions. Electronic structure and spectral properties of the complexes have been explained with the DFT and TDDFT calculation.
Keywords :
Ruthenium-carbonyl , DFT calculation , Electrochemistry , Thioarylazoimidazoles , X-ray structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
