Title of article :
Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases
Author/Authors :
Martin Jarenmark، نويسنده , , H?kan Carlsson، نويسنده , , Vladimir M. Trukhan، نويسنده , , Matti Haukka، نويسنده , , Sophie E. Canton، نويسنده , , Monica Walczak، نويسنده , , Wilfred Fullagar، نويسنده , , Villy Sundstr?m، نويسنده , , Ebbe Nordlander، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
The heterodinuclear complexes [FeZn(L)(CH3CO2)2]+ (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases. They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases.
Keywords :
Dinuclear , Transesterification , Model complexes , HPNP , Iron , zinc , Bioinorganic chemistry , Heterodinuclear , Purple acid phosphatase
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
