Title of article
The synthesis and characterization of a new butterfly-like polyoxometalate: K5Na2[Mo9V3O38]·9H2O
Author/Authors
Xue-Song Zang، نويسنده , , Hua-Qiao Tan، نويسنده , , Qiong Wu، نويسنده , , Yan Li، نويسنده , , Yangguang Li، نويسنده , , En-Bo Wang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
4
From page
471
To page
474
Abstract
A new butterfly-like compound K5Na2[Mo9V3O38]·9H2O 1 has been synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, TG analysis, UV–vis spectroscopy, X-ray photoelectron spectroscopy (XPS), cyclic voltammogram and single-crystal X-ray diffraction analysis. Compound 1 is a new butterfly-like molybdodivanadate composed by Mo (VI) and V (V) with the Mo/V ratio 3:1, the polyoxoanion [Mo9V3O38 ]7− can be described as two {MMo4O18} (M = Mo/V) units connected by one {V2O8} core. The photocatalyst property of compound 1 has been investigated, which shows a good photocatalyst for degradation of RhB.
Keywords
Polyoxometalate , Molybdodivanadate , Photocatalyze , Synthesis
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318445
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