Title of article
Reaction of the titanocene alkyne complex Cp2Ti(η2-Me3SiC2SiMe3) with selenium dioxide: Preparation and characterization of a novel tetranuclear titanium complex with selenium and oxo bridges
Author/Authors
Oliver Theilmann، نويسنده , , Martin Ruhmann، نويسنده , , Axel Schulz، نويسنده , , Alexander Villinger، نويسنده , , Uwe Rosenthal، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
3
From page
837
To page
839
Abstract
The low valent titanocene(II) source Cp2Ti(η2-Me3SiC2SiMe3) 1 reacts with selenium dioxide (2) to obtain a tetranuclear selenium and oxygen bridged titanocene(IV) [{Cp2Ti(µ2-O; µ2-Se)CpTi}2(µ2-O)] 6. The molecular structure was confirmed by X-ray analysis.
Keywords
titanocene , Ti(II) , Ti(IV) , Selenium dioxide
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318538
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