Title of article
A en-templated 3D coordination polymer based on H2pzdc with macrometallocycles
Author/Authors
Haining Wang، نويسنده , , Jun-Sheng Qin، نويسنده , , Dong-Ying Du، نويسنده , , Guang-Juan Xu، نويسنده , , Xinlong Wang ، نويسنده , , Kui-Zhan Shao، نويسنده , , Gang Yuan، نويسنده , , Lian-Jie Li، نويسنده , , Zhongmin Su، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
4
From page
1227
To page
1230
Abstract
A new Zn(II) coordination polymer, [Zn3(pzdc)4]·en (1) (H2pzdc = pyrazine-2,3-dicarboxylic acid, en = ethylenediamine), has been prepared under hydrothermal condition. X-ray diffraction analysis shows that 1 has a 3D structure with micropores (calcd. 4.074 × 6.444 Å2) along the [1 0 0] direction filled with en guest molecules. Notably, the pzdc groups connect Zn(II) cations to form a macrometallocycle as the subunit, which is further connected to generate the final framework. Additionally, the luminescent property of compound 1 has been investigated in detail.
Keywords
Coordination polymer , Macrometallocycle , Luminescence , Template , Zinc(II)
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318638
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