Title of article
A two-dimensional layered cadmium sulfide superlattice constructed from capped-supertetrahedral C1 clusters
Author/Authors
Xiao-Li Yang، نويسنده , , Jun Zhang، نويسنده , , Shi-Bin Ren، نويسنده , , Yi-Zhi Li، نويسنده , , Wei Huang، نويسنده , , Hongbin Du، نويسنده , , Xiao-Zeng You، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
3
From page
1337
To page
1339
Abstract
A new two-dimensional layered cadmium sulfide framework MSF-5 based on a capped-supertetrahedral C1 cluster [Cd17S4(SPhMe-4)27(SH)]2− has been synthesized. MSF-5 possesses a 3-connected 63–hcb net, in which each C1 cluster connects through Cd–S(PhMe-4)–Cd covalent bonds with three neighboring clusters to form a 2D superlattice with 6-membered rings. The 2D sheets stack over each other to form a 3D network. MSF-5 has high thermal stability and is a wide-gap semiconductor.
Keywords
CdS , Superlattice , Metal chalcogenide , Semiconductor , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318665
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