Title of article
Catalytic hydroboration of vinylarenes using a zwitterionic arylspiroboronate ester iridium complex
Author/Authors
Jennifer A. Melanson، نويسنده , , Christopher M. Vogels، نويسنده , , Andreas Decken، نويسنده , , Stephen A. Westcott، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
3
From page
1396
To page
1398
Abstract
Addition of B2cat3 (cat = 1,2-O2C6H4) to Ir(acac)(dppb) (1; where dppb = 1,4-bis(diphenylphosphino)butane) gave the novel arylspiroboronate ester iridium complex Ir(η6-catBcat)(dppb) (2), the first example of an iridium compound containing a coordinating [Bcat2]− anion. Complex is a remarkably selective catalyst precursor for the hydroboration of unhindered vinylarenes using pinacolborane.
Keywords
Arylspiroboronate ester , Catalysis , Hydroboration , Regioselectivity , Zwitterion
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318680
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