Title of article
Double O,C,O-chelated diorganotin(IV) cation
Author/Authors
Libor Dost?l، نويسنده , , Ale? R??i?ka، نويسنده , , Jaroslav Hole?ek، نويسنده , , Roman Jambor، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
3
From page
1470
To page
1472
Abstract
The synthesis of double O,C,O-chelated diorganotin(IV) compound L2SnBr2 (1), where L is 2,6-(MeOCH2)2C6H3−, the precursor for the synthesis of Sn ← O intramolecularly coordinated organotin(IV) cations is reported. Treatment of compound 1 with SnBr4 yielded the double O,C,O-chelated diorganotin(IV) ionic pair [L2SnBr]+ [SnBr5·THF]− (2). Both compounds 1 and 2 were characterized by 1H, 13C, 119Sn NMR and molecular structure of compound 2 was established by X-ray diffraction.
Keywords
Pincer ligands , Organotin , NMR , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318700
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