Title of article :
A peanut-like Keggin-type POM-incorporated metal-organic framework
Author/Authors :
Hong-Ying Zang، نويسنده , , Ke Tan، نويسنده , , Ya-Qian Lan، نويسنده , , Guang-Sheng Yang، نويسنده , , Kui-Zhan Shao، نويسنده , , Zhongmin Su، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Abstract :
A novel peanut-like POM-based metal-organic framework Cu3(BIMB)5(BIM)2(PMo12O40)2 has been successfully constructed. The metal-organic framework forms a peanut-like shell and {PMo12} anions embed in the voids to act as cores. The whole framework can be simplified as a (4,5)-connected 3D topology. In addition, we investigated the optical band gap of the title compound 2.84 eV.
Keywords :
Polyoxometalates , Metal-organic cage , CuII complex , Optical band gap
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
