Title of article :
Reaction of 9-trimethylsilylfluorenyllithium with nitriles: Organolithium compounds
Author/Authors :
Xia Chen، نويسنده , , Xiaoyan Xue، نويسنده , , Liping Zhang، نويسنده , , Wenhua Sun، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Abstract :
The reaction of 9-trimethylsilylfluorenyllithium (C13H8SiMe3)Li (1) with α-hydrogen-free nitriles gave highly sensitive lithium compounds, (η3-C13H8SiMe3)Li(tBuCN)(Et2O) (2), [η3-(C13H8)C(NMe2)N(SiMe3)]Li (Et2O)2 (3) and [η3,η6-(C13H8)C(Ph)N(SiMe3)Li]2 (4), illustrating bonding features of η3-allyl, η3-azaallyl, and η6-arene interactions.
Keywords :
?3-allyl , 9-trimethylsilylfluorenyllithium , ?6-Arene , ?3-azaallyl
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
