Title of article
Reaction of 9-trimethylsilylfluorenyllithium with nitriles: Organolithium compounds
Author/Authors
Xia Chen، نويسنده , , Xiaoyan Xue، نويسنده , , Liping Zhang، نويسنده , , Wenhua Sun، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
3
From page
235
To page
237
Abstract
The reaction of 9-trimethylsilylfluorenyllithium (C13H8SiMe3)Li (1) with α-hydrogen-free nitriles gave highly sensitive lithium compounds, (η3-C13H8SiMe3)Li(tBuCN)(Et2O) (2), [η3-(C13H8)C(NMe2)N(SiMe3)]Li (Et2O)2 (3) and [η3,η6-(C13H8)C(Ph)N(SiMe3)Li]2 (4), illustrating bonding features of η3-allyl, η3-azaallyl, and η6-arene interactions.
Keywords
?3-allyl , 9-trimethylsilylfluorenyllithium , ?6-Arene , ?3-azaallyl
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1318791
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