Title of article :
Unusual heterobimetallic palladium(II)–cerium(III) acetate complexes
Author/Authors :
Sergei E. Nefedov، نويسنده , , Natalia Yu. Kozitsyna، نويسنده , , Nailya S. Akhmadullina، نويسنده , , Natalia V. Cherkashina، نويسنده , , Michael N. Vargaftik، نويسنده , , Ilya I. Moiseev، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Pages :
4
From page :
554
To page :
557
Abstract :
Reaction of Pd3(μ-OOCMe)6 with CeIIIacetate in acetic acid is strongly water-dependent, producing the tetranuclear bis-paddlewheel [Pd(μ-OOCMe)4Ce(OH2)2(μ,η2-OOCMe)]2, pentanuclear cation-anionic [Pd(μ-OOCMe)4Ce(HOOCMe)2(OH2)2]+[Pd2Ce(μ-OOCMe)8]− × 2MeCOOH × 1.5H2O and 17-nuclear {[Pd(μ-OOCMe)4Ce(OOCMe)4]2[Pd4(μ-OOCMe)4]2(μ4-O)8CePd4}(OH)3 complexes.
Keywords :
Palladium , X-ray structure , Heterobimetallic complexes , Cerium
Journal title :
Inorganic Chemistry Communications
Serial Year :
2011
Journal title :
Inorganic Chemistry Communications
Record number :
1318871
Link To Document :
بازگشت