Title of article :
Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium(II) derived from 2-ferrocenyl-1,8-naphthyridine
Author/Authors :
C. Z??iga، نويسنده , , S.A. Moya، نويسنده , , M. Fuentealba، نويسنده , , B. Aranda، نويسنده , , P. Aguirre، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2011
Abstract :
2-Ferrocenyl-1,8-naphthyridine (1) and cis,cis,cis-dicarbonyl-dichloro-bis (2-ferrocenyl-1,8-naphthyridine) ruthenium(II) complex (2) have been synthesized and characterized by IR, 1H-NMR spectroscopy and elemental analysis. The structure of the compounds was determined by X-ray analysis. The complex (2) showed catalytic activity in the hydrogenation reaction of N-benzylideneaniline by hydrogen transfer with conversions between 89% and 33% for catalyst/substrate relations 200/1 and 400/1.
Keywords :
Ruthenium complex , Catalysts ruthenium , Hydrogenation imine
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications