Title of article
Synthesis and crystal structure of the first five-membered ansa-metallacyclocumulene rac-(ebthi)Zr(η4-t-Bu-C4-t-Bu)
Author/Authors
Vladimir V. Burlakov، نويسنده , , Yulia V. Nelyubina، نويسنده , , Konstantin A. Lyssenko، نويسنده , , Vladimir B. Shur، نويسنده , , Perdita Arndt، نويسنده , , Katharina Kaleta، نويسنده , , Wolfgang Baumann، نويسنده , , Uwe Rosenthal، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
3
From page
975
To page
977
Abstract
The zirconocene alkyne complex rac-(ebthi)Zr(η2-Me3SiC2SiMe3) (1) reacts with 1,4-bis-tert-butyl-buta-1,3-diyne to yield the novel five-membered metallacyclocumulene rac-(ebthi)Zr(η4-t-Bu-C4-t-Bu) (2) (ebthi = 1,2-ethylene-1,1′-bis(η5-tetrahydroindenyl)), t-Bu = tert-butyl). The structure of 2 was confirmed by X-ray studies.
Keywords
zirconocene , rac-(ebthi) , Metallacyclocumulene , ansa-metallocene , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1318970
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