Title of article
Highly efficient chemical fixation of carbon dioxide catalyzed by high-valent tetraphenylporphyrinatotin(IV) triflate
Author/Authors
Fatemeh Ahmadi-Abkenari، نويسنده , , Shahram Tangestaninejad، نويسنده , , Majid Moghadam، نويسنده , , Valiollah Mirkhani، نويسنده , , Iraj Mohammadpoor-Baltork، نويسنده , , Ahmad Reza Khosropour، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
5
From page
1489
To page
1493
Abstract
High-valent tetraphenylporphyrinatotin(IV) triflate, [SnIV(TPP)(OTf)2], was found as an efficient catalyst for the coupling of several epoxides (linear and cyclic) with carbon dioxide in the presence of tetrabutylphosphonium bromide as co-catalyst at atmospheric pressure. The reaction temperature, kind of solvent, co-catalyst and axial ligand effect were also investigated.
Keywords
Co-catalyst , p , Cyclic carbonates , Epoxides , CO2 fixation
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1319093
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