Title of article
Oxidation of benzyl alcohols to the corresponding carbonyl compounds catalyzed by copper (II) meso-tetra phenyl porphyrin as cytochrome P-450 model reaction
Author/Authors
Rahmatolah Rahimi، نويسنده , , Ensieh Gholamrezapor، نويسنده , , Mohammad Reza Naimi-jamal، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
8
From page
1561
To page
1568
Abstract
The oxidation of benzyl alcohols has been studied in the presence of isobutyraldehyde as co-catalyst, molecular oxygen as oxidant and copper (II) meso-tetra phenyl porphyrin (CuTPP) as catalyst. The CuTPP catalyst exhibits good activity and high selectivity under mild conditions. The effects of temperature and solvents have also been investigated in this catalyst system.
Keywords
Cytochrome P-450 , Copper (II) tetra phenyl porphyrin , molecular oxygen , Benzyl alcohols , Isobutyraldehyde , Oxidation
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1319111
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