Title of article
Novel synthetic method for cobalt complexes: Structural and kinetic study of [Co(nta)(py)(H2O)]
Author/Authors
N.I. Barnard، نويسنده , , H.G. Visser، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
3
From page
40
To page
42
Abstract
The synthesis, structural and solution properties of a novel cobalt aquo-pyridine complex [Co(nta)(py)(H2O)] (nta = nitrilotriacetate) are reported. Characterisation of the new complex was performed by 1H NMR, FTIR and single crystal X-ray diffraction. Substitution kinetics with NCS− ions over a large pH range indicates that pyridine induces a small cis effect.
Keywords
Cobalt , Nitrilotriacetate (NTA) , Pyridine , crystal structure , Substitution kinetics
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319221
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