Title of article
Palladiumd(II) complexes of N-{2-(aryltelluro)ethyl}morpholine/piperidine: Synthesis, structure, application in Heck coupling and unprecedented conversion into nano-sized PdTe
Author/Authors
Pradhumn Singh، نويسنده , , Dipanwita Das، نويسنده , , Arun Kumar، نويسنده , , Ajai K. Singh، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
4
From page
163
To page
166
Abstract
The complexes, [PdCl2(L)] (1–2) (L = N-{2-(aryltelluro)ethyl}morpholine/piperidine) have been synthesized and characterized by multi-nuclei NMR and single crystal X-ray crystallography. They on reaction with aryl chloride/bromide and morpholine/piperidine give ~ 5 nm size nano-particles of PdTe. The 0.005 mol% of 2 is suitable for Heck coupling (conversion up to 93%).
Keywords
Nano-particle , Heck coupling , structure , Palladium , Tellurium ligand , Synthesis
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319249
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