Title of article :
Palladiumd(II) complexes of N-{2-(aryltelluro)ethyl}morpholine/piperidine: Synthesis, structure, application in Heck coupling and unprecedented conversion into nano-sized PdTe
Author/Authors :
Pradhumn Singh، نويسنده , , Dipanwita Das، نويسنده , , Arun Kumar، نويسنده , , Ajai K. Singh، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
The complexes, [PdCl2(L)] (1–2) (L = N-{2-(aryltelluro)ethyl}morpholine/piperidine) have been synthesized and characterized by multi-nuclei NMR and single crystal X-ray crystallography. They on reaction with aryl chloride/bromide and morpholine/piperidine give ~ 5 nm size nano-particles of PdTe. The 0.005 mol% of 2 is suitable for Heck coupling (conversion up to 93%).
Keywords :
Nano-particle , Heck coupling , structure , Palladium , Tellurium ligand , Synthesis
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
