Title of article :
A 3D purely inorganic porous framework based on Keggin polyoxoanions
Author/Authors :
Xin-Bao Han، نويسنده , , Zhiming Zhang، نويسنده , , Zhi-Shu Wang، نويسنده , , Huan Zhang، نويسنده , , Hui Duan، نويسنده , , En-Bo Wang، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
A purely inorganic porous framework based on Keggin polyoxoanions K2NaH2[BW12O40]·12H2O (1) has been prepared and characterized by single-crystal X-ray analysis, IR and XRD analysis. Compound 1 crystallized in a chiral space group P6(4)22 with hexagonal symmetry. In compound 1, the 3D inorganic porous framework possesses of the 1D hexagon channels along the c axis. Furthermore, the porous framework exhibits reversible water sorption capability.
Keywords :
Keggin , Inorganic porous framework , Polyoxometalate
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications