Title of article
[Ni(dmit)2]− salt with flexible supramolecular cation rotator
Author/Authors
Qiong Ye، نويسنده , , Ping-Ping Shi، نويسنده , , Zi-Qi Chen، نويسنده , , Tomoyuki Akutagawa، نويسنده , , Shin-ichiro Noro، نويسنده , , Takayoshi Nakamura، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
6
From page
219
To page
224
Abstract
[Ni(dmit)2]− salt (dmit2− 2-thioxo-1,3-dithiole-4,5-dithiolate) with flexible supramolecular cation (4-cyanomethylanilinium)(dibenzo[18]crown-6) has been synthesized and investigated its structure, magnetism and rotation. The comparable large steric hindrances limit the rotation of cyanomethyl group to result in no phase transition occurred. Magnetic and potential energy calculations by DFT method were consistent with the magnetic and structure measurements.
Keywords
Molecular rotator , Flexible , Supramolecule , Crystal engineering
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319453
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