A mononuclear Mn2+ complex based on a novel tris-(ethyl acetate) pendant-armed tetraazamacrocycle: Effect of pyridine on self-assembly and weak interactions

A novel pyridine containing tetraazamacrocycle 3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene-3,6,9-triacetic acid ethyl ester (1) and its mononuclear Mn2+ complex (2) have been prepared. Pyridine induced the π–π stacking of [Mn1]2+ and provided donors for nonclassical Csingle bondH…O hydrogen bonding as well. In the solid state of 2, the combination of π–π interactions and hydrogen bonding constructed a 3D crystal structure and thus formed pairs of interacting mononuclear complexes that mediated weak magnetic exchanges between the Mn2+ ions. Meanwhile, self-assembly of 2 dissociated in the aqueous solution, and the effect of pyridine on the nature of DNA binding with 2 have also been investigated.