Title of article
A Mechanistic Description of Unexpected Room Temperature C-H and P-C Bond Activation by Wilkinsonʹs Catalyst
Author/Authors
Elvin Igart?a-Nieves، نويسنده , , Antonio J. Rivera-Brown، نويسنده , , José E. Cortés-Figueroa، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
4
From page
43
To page
46
Abstract
The Wilkinsonʹs catalyst, (PPh3)3RhCl dissolved in benzene under nitrogen or under high vacuum undergoes a series of unreported reactions at room temperature. The preliminary mechanistic description involves a series of consecutive intramolecular and intermolecular phosphine exchanges, benzene oxidative addition, and biphenyl reductive elimination.
Keywords
Oxidative addition , Metal hydride , Reductive elimination , Wilkinsonיs catalyst , Consecutive reactions , C-H bond activation
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319492
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