Title of article :
A new ferrocene-containing charge-transfer salt, (TTF)2[Fe(C5H4–CH(CH3)NHCOCH2SO3)2]
Author/Authors :
Naoya Kanbayashi، نويسنده , , Hiroki Akutsu، نويسنده , , Jun-ichi Yamada، نويسنده , , Shinʹichi Nakatsuji، نويسنده , , Scott S. Turner، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2012
Abstract :
A novel ferrocene-containing dianion, Fe(C5H4–CH(CH3)NHCOCH2SO3–)2 (1), has been prepared. The oxidation potential of the PPh4 salt is + 0.35 V (vs. SCE in PhCN), indicating that it is a stronger donor than TTF (tetrathiafulvalene) by + 0.03 V. The dianion provided a TTF salt, the structure and physical properties of which are reported.
Keywords :
Ferrocene , Tetrathiafulvalene , crystal structure , Charge-transfer salt , Organic conductors
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
