Title of article
A three-dimensional heterometallic MnIICuII azide-bridged coordination polymer: Synthesis, structure, and magnetic properties
Author/Authors
Zhi-Guo Gu، نويسنده , , Wen Zhou، نويسنده , , Fei-Fei Bao، نويسنده , , Chun-Yan Pang، نويسنده , , Xinxin Xu، نويسنده , , Zaijun Li، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
4
From page
22
To page
25
Abstract
A new three-dimensional heterometallic MnIICuII azide-bridged coordination polymer, [Mn2Cu(N3)6(en)2]n (1), was synthesized by assembling MnII, CuII, azide, and ethylenediamine in solution condition. The 3D structure of 1 can be described as end-on (EO) azide-bridged Mn2Cu trinuclear units linked by end-to-end (EE) azide bridges. Magnetic analysis of 1 indicates that the EO- and EE-azide bridges mediate the ferromagnetic and antiferromagnetic exchange interactions, respectively, with the antiferromagnetic coupling dominating the magnetic properties.
Keywords
Heterometallic , Azide-bridged , Three-dimensional , Magnetic properties
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319533
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