Title of article
The ionic nature of methylsulfur trichloride species
Author/Authors
Lucas S. Rodr?guez Pirani، نويسنده , , Mauricio F. Erben، نويسنده , , Carlos O. Della Védova، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
3
From page
66
To page
68
Abstract
The Raman spectrum of the methyldichloro-sulfonium(IV) chloride, CH3SCl2+Cl−, is reported. The unambiguous vibrational assignment for the CH3SCl2+ cation is made on the basis of the solid state Raman spectra aided by high-level quantum chemical calculations and a normal mode analysis. Actually, the former reported methylsulfur trichloride, CH3SCl3, can be now described as CH3SCl2+Cl−.
Keywords
sulfonium salts , Methyldichloro-sulfonium chloride , Ionic/covalent , Raman spectroscopy
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319705
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