Title of article
Synthesis, crystal structure and characterization of new tetranuclear Ag(I) complex with 5-aminoisophthalate
Author/Authors
Xiao-Wu Lei، نويسنده , , Fang-Xia Zhou، نويسنده , , Ming-Feng Wang، نويسنده , , Huiping Zhang، نويسنده , , Chengyang Yue، نويسنده , , Mao-Chun Hong، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
4
From page
171
To page
174
Abstract
One new AgI complex, [Ag2(aip)(NH3)]n (H2aip = 5-aminoisophthalic acid), has been prepared and structurally and spectroscopically characterized. The title complex crystallizes in the monoclinic system P21/c (no. 14) with a = 6.975(2) Å, b = 8.756(3) Å, c = 16.086(6) Å, β = 97.318(4)°, V = 974.4(6) Å3 and Z = 4. Its structure features a three-dimensional (3D) network composed of two-dimensional (2D) flexuous layer interconnected via weak hydrogen bonds. In aqueous solution, the H2aip exhibits blue emission, while the title complex with tetranuclear silver(I) cores and weak Ag…Ag bonds shows visible intense purple luminescence.
Keywords
Ag(I) , Coordination polymer , H2aip , Argentophilicity , Luminescence
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1319749
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