Title of article
Synthesis and characterization of bisphenol sodium complexes: An efficient catalyst for the ring-opening polymerization of l-lactide
Author/Authors
Xianrui Xu، نويسنده , , Xiaobo Pan، نويسنده , , Sifu Tang، نويسنده , , Xiaoxia Lv، نويسنده , , Liangjun Li، نويسنده , , Jincai Wu، نويسنده , , Xuebo Zhao، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
89
To page
93
Abstract
Two sodium complexes, [(μ3-MDBP)Na2(THF)2]2[(μ3-OCH2CH2OCH3)Na]2 (1) and [(μ1-MDBP)Na(μ2-H2O)(THF)]2(THF)2 (2) have been synthesized and structurally characterized. Experimental results show that complex 1 initiates efficiently the ring opening polymerization of l-lactide in a controlled fashion, yielding polymers with narrow polydispersity indexes in a wide range of monomer-to-initiator ratios.
Keywords
Sodium complexes , Catalyst , Polydispersity indexes , Ring opening polymerization
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1319795
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