Title of article
Dimeric aluminum methyl complex bridged by 2-oxy-2-methyl-1-(phenylamino)propane: Synthesis, structure, and use in ring opening polymerization of lactide
Author/Authors
Sungwoo Yoon، نويسنده , , So Han Kim، نويسنده , , Jungseok Heo، نويسنده , , Youngjo Kim، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
3
From page
157
To page
159
Abstract
A dimeric aluminum complex bridged by alkoxide with pendant aniline group was synthesized and characterized. X-ray analysis revealed that the two four-coordinate aluminum centers possess a distorted tetrahedral geometry with C2h symmetry. The compound was used as an effective catalyst for the controlled ring opening polymerization of L-lactide, as shown by the linearity of the number average of the molecular weight of polylactides versus conversion, as well as narrow Mw/Mn values.
Keywords
Aluminum , Dimeric , Polylactide , X-ray crystal structure , 2-Methyl-1-(phenylamino)propan-2-ol
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1319811
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