Title of article
Template synthesis, structure and electropolymerization of the 2-thiopheneboron-capped cobalt(II) clathrochelates
Author/Authors
Alexander S. Belov، نويسنده , , Alexander V. Dolganov، نويسنده , , Valentin V. Novikov، نويسنده , , Anna V. Vologzhanina، نويسنده , , Matvey V. Fedin، نويسنده , , Evgenii V. Kuznetsov، نويسنده , , Yurii N. Bubnov، نويسنده , , Yan Z. Voloshin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
160
To page
164
Abstract
2-thiopheneboron-capped macrobicyclic cobalt(II) tris-dioximates were synthesized by direct template condensation of the corresponding α-dioxime with 2-thiopheneboronic acid on a cobalt(II) ion as a matrix; they were characterized by spectral methods and X-ray crystallography. Further electropolymerization of their redox-active apical substituents afforded the polymeric clathrochelate electrocatalysts for hydrogen production from H+ ions.
Keywords
Macrocyclic compounds , Clathrochelates , cobalt complexes , Electropolymerization , Hydrogen production
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1319812
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