Title of article
Chemoselective synthesis of first representatives of bis(diorganothiophosphinyl)selenides, (R2P = S)2Se, from secondary phosphine sulfides and elemental selenium
Author/Authors
Alexander V. Artemʹev، نويسنده , , Ludmila A. Oparina، نويسنده , , Nina K. Gusarova، نويسنده , , Nikita A. Kolyvanov، نويسنده , , Oksana V. Vysotskaya، نويسنده , , Irina Yu. Bagryanskaya، نويسنده , , Boris A. Trofimov، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
4
From page
124
To page
127
Abstract
First bis(diorganothiophosphinyl)selenides, (R2P = S)2Se, have been synthesized in 74–86% yield by the chemoselective interaction of secondary phosphine sulfides with elemental selenium (1:1 molar ratio, 100 °C, 3 h, 1,4-dioxane); the alternative bis(diorganoselenophosphinyl)sulfides, (R2P = Se)2S, are not formed under these conditions.
Keywords
phosphine sulfides , crystal structure , Selenides , Thioselenophosphinate , Selenium
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1319852
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