• Title of article

    Spectroscopic characterization of titanocene complexes with thionucleobases

  • Author/Authors

    Enrique Meléndez-Hevia، نويسنده , , Mar??a Marrero، نويسنده , , Carmen Rivera، نويسنده , , Eliud Hern?ndez، نويسنده , , Alex Segal، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2000
  • Pages
    9
  • From page
    178
  • To page
    186
  • Abstract
    The reaction of Cp2TiCl2 with thionucleobases affords [Cp2Ti(L)]Cl2 complexes, where L=2-thiouracil, 6-thiopurine, 6-thioguanine, 2-thiocytosine, 6-thiopurineribose or 6-thioguanineribose. The ionic character of the chlorides has been determined by conductivity measurements and the coordination patterns of the thionucleobases have been determined by IR and proton NMR spectroscopies. The kinetics of ligand hydrolysis have been pursued to assess the stability of TiL and TiCp bonds in DMSO and DMSO–water solutions.
  • Keywords
    Antitumor agent , Titanocene complexes , Thionucleobase complexes
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2000
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1320173

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1320173