Title of article
Pentamethylcyclopentadienyl complexes of ruthenium(II) containing chiral diphosphines: reactivity towards BF3
Author/Authors
Franco Morandini، نويسنده , , Ingrid Munari، نويسنده , , Gian Andrea Rizzi، نويسنده , , Giambattista Consiglio، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
5
From page
142
To page
146
Abstract
Compounds (η5-C5Me5)Ru(L∧L)Cl (where L∧L is 2PPh3, 1,2-bis(diphenylphosphino)ethane or chiral homologs thereof) form adducts with BF3 that have a 1:2 stoichiometry. When the metal is a center of chirality, i.e. for complexes containing C1-symmetric diphosphines, the reaction takes place stereoselectively.
Keywords
Ruthenium complexes , Chiral diphosphine complexes , Pentamethylcyclopentadienyl complexes , Boron trifluoride complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2000
Journal title
INORGANICA CHIMICA ACTA
Record number
1320204
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