• Title of article

    Polyhedral azadicarbaborane chemistry. The ‘converse’ synthesis of a small family of 6,9-(NHR)-bridged-arachno-5,10-dicarbadecaboranes

  • Author/Authors

    Udo D?rfler، نويسنده , , Daniel L. Ormsby، نويسنده , , Robert Greatrex، نويسنده , , John D. Kennedy، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2000
  • Pages
    6
  • From page
    268
  • To page
    273
  • Abstract
    Addition of PhCCH to hypho-type species [(R′H2N)B8H11NHR] proceeds readily with the displacement of R′NH2 to give corresponding N-bridged arachno ten-vertex species [6,9-μ-(NHR)-5-Ph-arachno-5,10-C2B8H10] (15–34%), for which DFT structural and GIAO 11B nuclear shielding calculations suggest the syn configurations that have the R and Ph groupings on the same side of the molecule.
  • Keywords
    Boron cluster calculations , Azadicarborane chemistry
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2000
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1320437

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1320437