Title of article :
The structure of (η6-C6H5Cl)Cr(CO)2PPh3
Author/Authors :
Judith L Eglin، نويسنده , , Laura T Smith، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
In a synthetic route that varies from the standard procedure requiring irradiation, the (η6-C6H5Cl)Cr(CO)2PPh3 complex is obtained upon reacting (η6-C6H5Cl)Cr(CO)3 with tetrakis(triphenylphosphine)palladium(0), CuI, and trimethylsilylphenylacetylene in triethylamine. The X-ray crystal structure of the yellow–orange crystals of (η6-C6H5Cl)Cr(CO)2PPh3 allows structural comparisons to related (arene)Cr(CO)2PR3 complexes.
Keywords :
Carbonyl complexes , crystal structure , Chloroarene complexes , chromium complexes
Journal title :
INORGANICA CHIMICA ACTA
Journal title :
INORGANICA CHIMICA ACTA
