Title of article
Kinetics of the photoreduction of bis(2,4-pentanedionato)copper(II) in chloroform
Author/Authors
Wilson Ng، نويسنده , , Patrick E. Hoggard، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
4
From page
1
To page
4
Abstract
Under 254 nm irradiation in chloroform, bis(2,4-pentanedionato)copper(II) is converted to CuCl·2HCl, from which CuCl precipitates at concentrations of 10−3 M or higher. The photoreaction appears to be completely solvent-initiated, that is, the rate depends on the fraction of light absorbed by the solvent. Both radical dotCCl3 radicals and HCl, produced photolytically, are able to initiate the reaction.
Keywords
Acetylacetonato complexes , Photoreduction , Chloroform , Solvent-initiated , Bis(2 , 4-pentanedionato)copper(II)
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2001
Journal title
INORGANICA CHIMICA ACTA
Record number
1320916
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