• Title of article

    Dirhenium and dimolybdenum complexes of di(isopropylphosphino)methane

  • Author/Authors

    Huifang Lang، نويسنده , , Phillip E. Fanwick، نويسنده , , Richard A. Walton، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    6
  • From page
    17
  • To page
    22
  • Abstract
    The first multiply bonded dimetal complexes that contain the bridging phosphine ligand Pr2iPCH2PPr2i (dippm) have been isolated and structurally characterized. The dimolybdenum(II) and dirhenium(III,II) complexes Mo2Cl4(μ-dippm)2 and [trans-Re2(μ-O2CCH3)2Cl2(μ-dippm)2]Cl0.74(ReO4)0.26 have MM distances of 2.1699(3) and 2.2705(3) Å, respectively, in accord with and bond orders. Attempts to isolate Re2Cl4(μ-dippm)2 led instead to the dirhenium(V) complex Re2O3Cl4(μ-dippm)2, structurally analogous to the previously isolated Re2O3Cl4(μ-dppm)2 (dppm=Ph2PCH2PPh2).
  • Keywords
    crystal structures , Metal–metal multiple bonds , Dirhenium complexes , Dimolybdenum complexes , Bridging phosphine ligands
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2001
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1320949

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1320949