Title of article
Phosphite derivatives of (2R)-2-pyrrolidin-1-yl-butan-1-ol: synthesis, chelation with rhodium(I) and testing in the palladium-catalysed allylic alkylation
Author/Authors
Alexei I Polosukhin، نويسنده , , Oleg G Bondarev، نويسنده , , Andrei V Korostylev، نويسنده , , Robert Hilgraf، نويسنده , , Vadim A. Davankov، نويسنده , , Konstantin N. Gavrilov، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
7
From page
55
To page
61
Abstract
A series of chiral phosphite-type ligands with pyrrolidine moieties was synthesised. The compounds form chelate complexes upon reaction with [Rh(CO)2Cl]2. The new ligands were tested in Pd-catalysed enantioselective allylic alkylation giving up to 61% ee under standard conditions.
Keywords
N-ligands , Rhodium complexes , Phosphites , Allylic Alkylation , Chiral P
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2001
Journal title
INORGANICA CHIMICA ACTA
Record number
1320976
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