Title of article
Reactivity towards dioxygen of a copper(I) complex of tris(2-benzylaminoethyl)amine
Author/Authors
Markus Schatz، نويسنده , , Michael Becker، نويسنده , , Olaf Walter، نويسنده , , Günter Liehr، نويسنده , , Siegfried Schindler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
7
From page
173
To page
179
Abstract
The reaction of dioxygen with the copper(I) Bz3tren complex (Bz3tren=tris(2-benzylaminoethyl)amine) complex has been investigated using low temperature stopped-flow techniques. The formation of a superoxo as well as a peroxo complex as intermediates was detected spectroscopically. The copper(II) complexes [Cu(Bz3tren)H2O](ClO4)2 and [Cu(Bz3tren)Cl]Cl were synthesized and structurally characterized. Both complexes react with dioxygen in solution and formation of benzaldehyde was observed.
Keywords
Dioxygen activation , Peroxo/superoxo complexes , Copper complexes , Tripodal ligands
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2001
Journal title
INORGANICA CHIMICA ACTA
Record number
1321011
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