• Title of article

    Reaction of the [WSe4]2− anion with phosphines: synthesis and crystal structure of a novel cubane-like cluster [W2Se4(η2-Se2CH2)2{Cu(PCy3)}2] (Cycyclohexyl)

  • Author/Authors

    Qian-Feng Zhang، نويسنده , , Kwok-Kin Lau، نويسنده , , Wai Yeung Wong، نويسنده , , Wa-Hung Leung، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    5
  • From page
    125
  • To page
    129
  • Abstract
    Treatment of [Et4N]2[WSe4] with an excess of PPh3 gives the W(V) dimer [Et4N]2[W2Se6]. Reaction of [Et4N]2[WSe4] with PCy3 (Cycyclohexyl) in the presence of [CuCl] in CH2Cl2 affords [(μ-WSe4){Cu(PCy3)}{Cu(PCy3)2}] along with a cubane-like cluster [W2Se4(η2-Se2CH2)2{Cu(PCy3)}2], which has been characterized by X-ray crystallography.
  • Keywords
    Phosphine ligands , Cubane-like cluster , Heteroselenometalate , crystal structures
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2001
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1321050

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1321050