Title of article
Oxalato complexes of Re(V). Synthesis and structural characterization of [ReO(OCH3)(ox)(L)] (L=bipy, dppe and dppee)
Author/Authors
Ra?l Chiozzone، نويسنده , , Ricardo Gonz?lez، نويسنده , , Carlos Kremer، نويسنده , , Giovanni De Munno، نويسنده , , Juan Faus، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
5
From page
203
To page
207
Abstract
Two kinds of optically active hydrazides reacted with three tetrahedron-type clusters, respectively, to form hydrazone cluster diastereoisomers, intending to separate racemic clusters. However, the mixture of diastereoisomers cannot be separated into single diastereoisomer by silica gel chromatography. The 1H and 13C NMR spectra established their presence.
Keywords
Transition metal , Chiral , crystal structures , Enantiomeric separation , Diastereoisomers , Cluster complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2001
Journal title
INORGANICA CHIMICA ACTA
Record number
1321062
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