• Title of article

    Unexpected orthopalladation of acetophenonephenylhydrazone

  • Author/Authors

    Arancha Carbayo، نويسنده , , Gabriel Garc??a-Herbosa، نويسنده , , Santiago Garcia-Granda، نويسنده , , Daniel Miguel، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2002
  • Pages
    5
  • From page
    260
  • To page
    264
  • Abstract
    A singular hydrazonato complex of palladium has induced the unexpected orthometallation of acetophenonephenylhydrazone on the phenyl group. This is the first X-ray characterized example of an orthopalladated E-arylhydrazone of general formula ArC(R″)NNHAr′ where the metallated aryl is Ar′ although palladation on Ar is not hindered. Structural evidence suggests that the PdN(amido) bond that is present in the starting material induced the palladation of the unexpected phenyl.
  • Keywords
    Palladium , arylhydrazones , Orthopalladation
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2002
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1321472

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1321472