• Title of article

    New homobinuclear carboxylate-bridged gadolinium(III) complexes

  • Author/Authors

    Alberto Rizzi، نويسنده , , Ricardo Baggio، نويسنده , , Maria T Garland، نويسنده , , Octavio Pena، نويسنده , , Mireille Perec، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    5
  • From page
    315
  • To page
    319
  • Abstract
    Two novel gadolinium(III) trans-2-butenoate dimeric compounds [Gd2(O2CCHCHCH3)6(H2O)4]·2H2O (1) and [Gd2(O2CCHCHCH3)6(phen)2]·2H2O (2) have been synthesized via hydrothermal routes. Compound 1 consists of two independent dimers in the unit cell, one is doubly bridged (η2:η1:μ2) and the other quadruply bridged (two η1:η1:μ2 and two η2:η1:μ2). Compound 2 is dimeric with a quadruply bridged core (two η1:η1:μ2 and two η2:η1:μ2). Magnetic measurements for 2 show that there is a weak antiferromagnetic intramolecular Gd⋯Gd interaction.
  • Keywords
    Gadolinium dimers , Carboxylate complexes , Magnetism , Structural chemistry
  • Journal title
    INORGANICA CHIMICA ACTA
  • Serial Year
    2003
  • Journal title
    INORGANICA CHIMICA ACTA
  • Record number

    1321793

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1321793