Title of article
Reactivity of 2,6-diethyl-4,8-dimethyl-1,5-dioxo-s-hydrindacene towards radical, anionic and cationic germylation
Author/Authors
A. El Kadib، نويسنده , , A. Castel، نويسنده , , F. Delpech، نويسنده , , J. P. RIVIERE، نويسنده , , M. Rivière-Baudet، نويسنده , , H. Gornitzka، نويسنده , , P. Aguirre، نويسنده , , J.M. Manriquez، نويسنده , , Pedro I. Chavez، نويسنده , , D. Abril، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
9
From page
1256
To page
1264
Abstract
The synthesis and diastereoisomeric resolution of 2,6-diethyl-4,8-dimethyl-1,5-dioxo-s-hydrindacene allowed the determination of the structure of the meso compound by X-ray diffractometry. The diastereoisomers were inactive towards radical germylation but reacted with acidic hydrogermanes or germylithium yielding α-germylated alcohols. By contrast, they were poorly reactive towards germylamines or SET reactions. This diketone acts as an efficient spin trap in radical hydrogermylation of alkenes.
Keywords
6-Diethyl-4 , 2 , 5-dioxo-s-hydrindacene , Germylation , 8-dimethyl-1 , Radical inhibitor , Hydrogermylation
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2004
Journal title
INORGANICA CHIMICA ACTA
Record number
1322041
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